I'm taking a few liberties guessing what you might be requiring here as your description is not clear, but I think you might be asking if you can adjust the content type from text/xml to something else... if so, yes, and the following thread describes how:
One way could be to just call the webservice asynchronously (use a BPM if you need a sync/async bridge) and then have the webservice server to send the response when available to the receiver as a different scenario, that also could be a webservice or an HTTP server. You could also make this communication inside a BPM and use correlation to detect inside the BPM that the answer that you are receiving matches with the async webservice previously made.
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