In normal circumstances, system will consider payment term from Sold To and I am not sure, whether you have checked this before posting here. If Sold To and Payer are different, then system will give preference to Payer. If you want to fetch from Bill To, then you have to go with exit for which, similar topic has already been discussed here.
Take the inputs from there and do coding changes suitably
G. Lakshmipathi
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