1. If you donot have any line items which are Order related billing, then you can NOT see any billing status in the sales order
2. ONLY when you have a line item which is Order related billing (with or without delivery related billing line items) then there is an additional field populating in the sales order (VA02, 3), which gives you the billing status, both at header and line item level.
On a general note - SAP has really made a great product (ERP system)
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