FA(New)>FAGlobal Settings(New)>Witholding Tax-->Extended Witholding Tax here you need to configure payment WTtype and WTCode and give the requisite percentage. The same WTT & WTCode need to be incorporated/maintained in Vendor Master.
Sorry by mistake I said Vendor master but it should have been customer master. Configuration is same except that while assigning withholding tax type to company code you select subject to w/tx under customer data . Just differentiate the section code with prefix 2 instead of 1 to have distinction.
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