Happy to note you have found the solution on your own. At the sametime, if would have been wonderful had you updated the forum as to how you solved on your own so that it will be helpful for all.
In sale order at header level, you can see a tab "Billing Document", where you can also see a field "Financial doc. no.". Once you have created the LC in VX11N, the reference number has to be assigned here.
Export license is different than Letter of Credit.
Export license falls under legal control where as Letter of Credit is a documentary Payment process. The field you are telling about is to assgn the letter of credit number and not the Export license.
Well after exploring from the system i found that sales order has to be activated for legal control and material master data has to be mainted in foreign trade data with export class. Once Export license is made for a particular customer, system checks the material and Customer for export license and it is determined in sales order.
You can see it in sales order under Menu Extras --- Export license --- Export Control data.
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