Go to T.code VV31 and select the billing output type and select the access sequence required and in the details screen of create condition records give all the required entries for eg: may be Billing Type, Sales Organsiation etc.and in the medium choose the option as 6(EDI) and time select as 4 that is immediately after saving the document.Also please ensure that particular partners for whom idoc should be generated they need to have partner profile setup with the billing message types. Hope this helps.
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